Stream temperature is a key physical water‐quality parameter, controlling many biological, chemical, and physical processes in aquatic ecosystems. Maintenance of cool stream temperatures during summer is critical for high‐quality aquatic habitat. As such, transmission of warm water from small, nonfish‐bearing headwater streams after forest harvesting could cause warming in downstream fish‐bearing stream reaches with negative consequences. In this study, we evaluate (a) the effects of contemporary forest management practices on stream temperature in small, headwater streams, (b) the transmission of thermal signals from headwater reaches after harvesting to downstream fish‐bearing reaches, and (c) the relative role of lithology and forest management practices in influencing differential thermal responses in both the headwater and downstream reaches. We measured summer stream temperatures both preharvest and postharvest at 29 sites—12 upstream sites (4 reference, 8 harvested) and 17 downstream sites (5 reference, 12 harvested)—across 3 paired watershed studies in western Oregon. The 7‐day moving average of daily maximum stream temperature (T7DAYMAX) was greater during the postharvest period relative to the preharvest period at 7 of the 8 harvested upstream sites. Although the T7DAYMAX was generally warmer in the downstream direction at most of the stream reaches during both the preharvest and postharvest period, there was no evidence for additional downstream warming related to the harvesting activity. Rather, the T7DAYMAX cooled rapidly as stream water flowed into forested reaches ~370–1,420 m downstream of harvested areas. Finally, the magnitude of effects of contemporary forest management practices on stream temperature increased with the proportion of catchment underlain by more resistant lithology at both the headwater and downstream sites, reducing the potential for the cooling influence of groundwater. 相似文献
As managed retreat programs expand across the globe, there is an urgent need to assess whether these programs are reducing exposure to climatic hazards, enhancing adaptive capacity, and improving the living conditions of communities in a just and equitable manner or are they exacerbating existing risks and vulnerabilities? Strictly speaking, are retreat programs successful? Using an expansive intersectional justice approach to examine 138 post-resettlement case studies published between 2000 and 2021 across the Global North and South, we identified five typologies of success – techno-managerial, eco-restorative, compensatory, reformative, and transformative – and their trade-offs and synergies. Our meta-analysis incorporated a variety of metrics: relocation types, funding, decision making, socio-economic class, land use change, livelihood options, and social impacts. We found 26% of cases failed, 43% were successful, and 30% are on-going and therefore success was undetermined. The techno-managerial cases, while successful in the limited terms of relocating residents, paid little attention to equity and justice. The eco-restorative and compensatory cases reduced hazard exposure but revealed the synergies and tensions associated with social, ecological, and intergenerational justice. The reformative and transformative cases improved community wellbeing, rootedness, and access to livelihoods while incorporating diverse justice concerns to different degrees. By intersecting these typologies with multiple dimensions of justice, this study advances a novel planning and analytical tool for assessing the potential success or failure of current and future retreat programs. 相似文献
Sequestration of organic carbon (OC) in environmental systems is critical to mitigating climate change. Organo-mineral associations, especially those with iron (Fe) oxides, drive the chemistry of OC sequestration and stability in soils. Short-range-ordered Fe oxides, such as ferrihydrite, demonstrate a high affinity for OC in binary systems. Calcium commonly co-associates with OC and Fe oxides in soils, though the bonding mechanism (e.g., cation bridging) and implications of the co-association for OC sequestration remain unresolved. We explored the effect of calcium (Ca2+) on the sorption of dissolved OC to 2-line ferrihydrite. Sorption experiments were conducted between leaf litter-extractable OC and ferrihydrite at pH 4 to 9 with different initial C/Fe molar ratios and Ca2+ concentrations. The extent of OC sorption to ferrihydrite in the presence of Ca2+ increased across all tested pH values, especially at pH ≥ 7. Sorbed OC concentration at pH 9 increased from 8.72 ± 0.16 to 13.3 ± 0.20 mmol OC g?1 ferrihydrite between treatments of no added Ca2+ and 30 mM Ca2+ addition. Batch experiments were paired with spectroscopic studies to probe the speciation of sorbed OC and elucidate the sorption mechanism. ATR-FTIR spectroscopy analysis revealed that carboxylic functional moieties were the primary sorbed OC species that were preferentially bound to ferrihydrite and suggested an increase in Fe-carboxylate ligand exchange in the presence of Ca at pH 9. Results from batch to spectroscopic experiments provide significant evidence for the enhancement of dissolved OC sequestration to 2-line ferrihydrite and suggest the formation of Fe–Ca-OC ternary complexes. Findings of this research will inform modeling of environmental C cycling and have the potential to influence strategies for managing land to minimize OM stabilization. 相似文献
Minerals constitute a primary ecosystem control on organic C decomposition in soils, and therefore on greenhouse gas fluxes to the atmosphere. Secondary minerals, in particular, Fe and Al (oxyhydr)oxides—collectively referred to as “oxides” hereafter—are prominent protectors of organic C against microbial decomposition through sorption and complexation reactions. However, the impacts of Mn oxides on organic C retention and lability in soils are poorly understood. Here we show that hydrous Mn oxide (HMO), a poorly crystalline δ-MnO2, has a greater maximum sorption capacity for dissolved organic matter (DOM) derived from a deciduous forest composite Oi, Oe, and Oa horizon leachate (“O horizon leachate” hereafter) than does goethite under acidic (pH 5) conditions. Nonetheless, goethite has a stronger sorption capacity for DOM at low initial C:(Mn or Fe) molar ratios compared to HMO, probably due to ligand exchange with carboxylate groups as revealed by attenuated total reflectance-Fourier transform infrared spectroscopy. X-ray photoelectron spectroscopy and scanning transmission X-ray microscopy–near-edge X-ray absorption fine structure spectroscopy coupled with Mn mass balance calculations reveal that DOM sorption onto HMO induces partial Mn reductive dissolution and Mn reduction of the residual HMO. X-ray photoelectron spectroscopy further shows increasing Mn(II) concentrations are correlated with increasing oxidized C (C=O) content (r = 0.78, P < 0.0006) on the DOM–HMO complexes. We posit that DOM is the more probable reductant of HMO, as Mn(II)-induced HMO dissolution does not alter the Mn speciation of the residual HMO at pH 5. At a lower C loading (2 × 102 μg C m?2), DOM desorption—assessed by 0.1 M NaH2PO4 extraction—is lower for HMO than for goethite, whereas the extent of desorption is the same at a higher C loading (4 × 102 μg C m?2). No significant differences are observed in the impacts of HMO and goethite on the biodegradability of the DOM remaining in solution after DOM sorption reaches steady state. Overall, HMO shows a relatively strong capacity to sorb DOM and resist phosphate-induced desorption, but DOM–HMO complexes may be more vulnerable to reductive dissolution than DOM–goethite complexes. 相似文献
The paper describes a multi-phase, multi-scale rational method for modeling and predicting free-field wave propagation and the weakening and liquefaction of near-surface soils. The one-dimensional time-domain model of a soil column uses the discrete element method (DEM) to track stress and strain within a series of representative volume elements (RVEs), driven by seismic rock displacements at the column base. The RVE interactions are accomplished with a time-stepping finite-difference algorithm. The method applies Darcy’s principle to resolve the momentum transfer between a soil’s solid matrix and its interstitial pore fluid. Different algorithms are described for the dynamic period of seismic shaking and for the post-shaking consolidation period. The method can analyze numerous conditions and phenomena, including site-specific amplification, down-slope movement of sloping ground, dissolution or cavitation of air in the pore fluid, and drainage that is concurrent with shaking. Several refinements of the DEM are described for realistically simulating soil behavior and for solving a range of propagation and liquefaction factors, including the poromechanic stiffness of the pore fluid and the pressure-dependent drained stiffness of the grain matrix. The model is applied to four sets of well-documented centrifuge studies. The verification results are favorable and highlight the importance of the pore fluid conditions, such as the amount of dissolved air within the pore water.
The Ediacaran Jibalah Group comprises volcano‐sedimentary successions that filled small fault‐bound basins along the NW–SE‐trending Najd fault system in the eastern Arabian‐Nubian Shield. Like several other Jibalah basins, the Antaq basin contains exquisitely preserved sedimentary structures and felsic tuffs, and hence is an excellent candidate for calibrating late Ediacaran Earth history. Shallow‐marine strata from the upper Jibalah Group (Muraykhah Formation) contain a diversity of load structures and intimately related textured organic (microbial) surfaces, along with a fragment of a structure closely resembling an Ediacaran frond fossil and a possible specimen of Aspidella. Interspersed carbonate beds through the Muraykhah Formation record a positive δ13C shift from ?6 to 0‰. U‐Pb zircon geochronology indicates a maximum depositional age of ~570 Ma for the upper Jibalah Group, consistent with previous age estimates. Although this age overlaps with that of the upper Huqf Supergroup in nearby Oman, these sequences were deposited in contrasting tectonic settings on opposite sides of the final suture of the East African Orogen. 相似文献
The expansion of multinational corporations into agricultural production around the world is resulting in new forms of engagement in specific places. In the context of neoliberal restructuring, these engagements are tied to shifting landscapes of societal, governmental and industry-based perceptions on the role of corporations in labor regimes. But how are these engagements developed and how do they connect to the everyday lives of workers? In India, when Monsanto expanded into hybrid cotton seed production in the early 2000s, the corporation came under pressure to address concerns over the widespread employment of children and young workers for seed pollination. In response, the corporation developed an approach to child labor that, I argue, works to reinforce generalized and problematic notions of childhood and work. Corporate engagements in global agriculture need to be situated in time and space, and alongside the experiences of workers. Children experience attempts to shape their patterns of work and mobility as a series of surmountable obstacles, disconnected from the process of deciding whether or not they will engage in this work. Drawing on qualitative fieldwork in Gujarat and Rajasthan, and documentary analysis of public documents, I outline the development of a corporate response to child labor and place it within the context of the rise of corporate social responsibility, global ideas of child labor, and in the specific case of cotton seed production in western India. I demonstrate that contextualized geographies of working children in globalized agriculture reveal the nature of multinational corporations’ engagements in specific places. 相似文献
Benthic macroalgae form an important part of temperate marine ecosystems, exhibiting a complex three-dimensional character which represents a vital foraging and spawning ground for many juvenile fish species. In this research, image-based techniques for classification of multibeam backscatter are explored for the detection of benthic macroalgae at Cashes Ledge in the Gulf of Maine, USA. Two classifications were performed using QTC-Multiview, differentiated by application of a threshold filter, and macroalgal signatures were independently extracted from the raw sonar datagrams in Matlab. All classifications were validated by comparison with video ground-truth data. The unfiltered classification shows a high degree of complexity in the shallowest areas within the study site; the filtered demonstrates markedly less variation by depth. The unfiltered classification shows a positive agreement with the video ground-truth data; 82.6% of observations recording Laminaria sp., 39.1% of Agarum cribrosum and 100.0% (n = 3) of mixed macroalgae occur within the same acoustically distinct group of classes. These are discrete from the 8.1% recorded agreement with absences and nulls (>40 m) of macrophytes (n = 32) from a total of 86 ground-truth locations. The results of the water column data extraction (WCDE) show similar success, accurately predicting 78.3% of Laminaria sp. and 30.4% of A. cribrosum observations. 相似文献